The Element Silver


A comprehensive guide to silver, from its atomic structure to fundamental physical properties to basic history. Silver is a soft, white, lustrous transistion metal that has the highest electrical conductivity and highest thermal conductivity of any metal. The existence of silver has been known since ancient times, and is one of the few metals many recognize by name in more than one language.

  • English: Silver
  • Spanish: Plata
  • German: Silber
  • Latin: Argentum
  • Italian: Argento
  • French: Argent
  • Polish: Srebrny
  • Dutch: Zilver
  • Finish: Hopea
  • Norwegion: sølv

Periodic Table Properties

39
8
26
5
28
Ni
   Nickel   
36
7
27
2
23
Cu
Copper
40
10
25
5

30
Zn
    Zinc    
45
11
28
6
46
Pd
Palladium
71
33
36
2
47
Ag

Silver

51
13
32
6

48
Cd
Cadmium
47
10
32
5
78
Pt
Platinum
70
33
36
1
79
Au
Gold
56
16
33
7
80
Hg
Mercury

Silver’s Atomic Structure

Silver's Atomic Structure

 
Specific Silver Properties
 
Silver’s Five Energy Shell Levels
    Atomic Number: 47 Atomic Symbol: Ag              First Energy Level: 2 Second Energy Level: 8
  Atomic Weight: 107.868 Total Isotopes: 71   Third Energy Level: 18 Fourth Energy Level: 18
  Total Isomers: 33 Radioactive Isoteps: 36   Fifth Energy Level: 1  
  Table Isoteps: 2 Group number: 11      

Silver History

The attractive nature of silver is self evident. It has been used for thousands of years for many, many things. Interestingly, silver has some traits that standout above all other metals. Did you know silver has?

  • The whitest color
  • The highest optical reflectivity
  • The highest thermal conductivity
  • The highest electrical conductivity

Generally speaking, the majority of today’s mining operations that produce silver are after much more. Silver occurs with other base metals, like gold, copper, zinc and lead. It’s these metals that are typically the thrust of many mines. Silver is just another benefit or byproduct of them.

Obviously, as price adjustments happen with silver the focus or priority of mining it can shift. However, that shifting isn’t as much as one would think. Because silver has properties that make it extremely useful in electronics and photography, a significant portion of its demand is driven by needs rather than price.

In recent history, there have been major events that have resulted in silver price changes:

1985

U.S. Mint authorized to begin minting a silver bullion coin

1979-80

Attempt to corner the silver market

1968

Redemption of silver certificates for silver could only be made until June 24; thereafter, silver certificates would be exchanged for Federal Reserve Notes

1967

Announcement by U.S. Government that all silver coins would be withdrawn from circulation

1965

Silver eliminated from all U.S. coins except the half dollar, which has its silver content reduced from 90% to 40%

1963

Silver Purchase Act and various other legislation repealed; U.S. Treasury authorized to print Federal Reserve Notes, which were not redeemable for silver, for circulating currency

1950-68

Huge U.S. Government silver holdings largely depleted

(Source of data: U.S. Geological Survey)

Silver Phyiscal Properties & Basic Information

Phase: Solid
Magnetic Ordering: Diamagnetic
Classification: Transition Metal
Electrical Resistivity: (20 °C) 15.87 n Ω·m
Mass: 107.8682
Thermal Conductivity: (300 K) 429  W·m−1·K−1
Hardness: 3.25 mohs
Thermal Diffusivity: (300 K) 174 mm²/s
Density @ 293 K: 10.49  g/cm3
Thermal Expansion: (25 °C) 18.9  µm·m−1·K−1
Atomic Volume: 10.3 cm3/mol
Speed of sound (thin rod): (r.t.) 2680  m·s−1
Liquid Density at m.p.: 9.320  g·cm−3
Young’s modulus: 83  GPa
Melting Point: 1234.93 K (961.78 °C, 1763.2 °F)
Shear modulus: 30  GPa
Boiling Point: 2435 K (2162 °C, 3924 °F)
Bulk modulus: 100  GPa
Heat of Fusion: 11.28  kJ·mol−1
Poisson ratio: 0.37
Heat of Vaporization: 250.58  kJ·mol−1
Mohs hardness: 2.5
Specific Heat Capacity: (25 °C) 25.350  J·mol−1·K−1
Vickers hardness: 251  MPa
CAS registry number: 7440-22-4
Brinell hardness: 24.5  MPa

Radius:

ionic radius (2- ion): pm
ionic radius (1- ion): pm
atomic radius: 144 pm
ionic radius (1+ ion): 129 pm
ionic radius (2+ ion): 108 pm
ionic radius (3+ ion): 89 pm

 

Reactions

With air: mild, =>Ag2O
With 6M HCl: none
With 6M HCl: none
With 15M HNO3: mild, =>AgNO3

Silver Half Lives:

Isotope
Half Live
Ag105
41.3 days
Ag105m
7.2 minutes
Ag106m
8.4 days
Ag107
stable
Ag108
2.4 minutes
Ag108m
130 years
Ag109
stable
Ag109m
39.8 seconds
Ag110
24.6 seconds
Ag110m
249.8 days
Ag111
7.47 days